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- Heat a large cast iron skillet over medium-high heat. Add the ground beef and cook until it forms a deep brown crust on the underside before breaking it up.
- Continue to cook the beef, stirring occasionally, until about 50% of it is deeply browned.
- Remove the beef from the skillet, leaving the fat behind. Add the butter, diced onions, green bell peppers, and mushrooms to the skillet.
- Allow the vegetables to brown for 1-2 minutes without stirring, then stir and let them brown for another 1-2 minutes.
- Return the browned beef to the skillet.
- In a small cup, mix the beef broth and cornstarch together until smooth.
- Stir in the ketchup, Worcestershire sauce, salt, black pepper, and the beef broth-cornstarch mixture to the skillet with the beef and vegetables.
- Cook the mixture over medium heat until it thickens but is still slightly liquidy, about 3-5 minutes.
- Turn off the heat and mix in the chopped Provolone cheese until melted and well combined.
- Serve the sloppy joe mixture on toasted brioche buns.
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